Why should an HII region
emit radio radiation at all?
Because charged particles are being accelerated electrostatically, and
free accelerated charges radiate according to Larmor's
formula. Recall
that only the component of the electric field perpendicular to the
line-of-sight contributes to the electromagnetic radiation at large
distances $r$:
$$E_\bot = {q \dot{v} \sin \theta \over r c^2} ,$$
where
$q$ is the charge, $\theta$ is the angle between the acceleration
$\dot{v}$ and the line-of-sight to the observer, and $c$ is the speed
of light.
All manner of electrostatic
interactions between various charged particles take place in an HII
region, but most do not emit significant amounts of
radiation. The magnitude of the acceleration is equal to the Coulomb
force
$$ F = { q_1 q_2 \over r^2_{12}}$$
divided by the particle mass $m$.
The mass of even the lightest ion (the mass of a hydrogen ion is the
proton
mass $m_{\rm p} \approx 1.66 \times 10^{-24}$ g) is about two
thousand times the electron
mass $m_{\rm e} \approx 9.11 \times
10^{-28}$ g. In an electron-ion collision, the electron will therefore
radiate at least $({m_{\rm p} / m_{\rm e}})^2 \approx 4 \times 10^6$ as
much power as the ion, so we may ignore as negligible the radiation
from all of the ions. Interactions between identical particles also do
not radiate
significantly because the accelerations of the two particles are equal
in magnitude but opposite in direction: $\dot{v_1} = -\dot{v_2}$. Thus
their radiated electric fields are equal in magnitude but opposite in
sign; the net $E_\bot$ approaches zero at large distances where $r
\approx r_1 \approx r_2$. We can therefore ignore the radiation from
electron-electron collisions. Only
electron-ion collisions are
important, and only the electrons radiate.
Consider the radiation from an
electron passing by a much more
massive ion of charge $Ze$, where $Z = 1$ for a singly ionized atom
like hydrogen. Each electron-ion interaction will generate a single
pulse of radiation. We will calculate the total energy emitted and the
(approximate) frequency spectrum of the pulse. The exact spectrum of an
individual pulse will
not be needed since there is a broad distribution of electron energies
and impact parameters to smear out such detail in the total spectrum
of an HII region.

Radio photons are produced by weak interactions, meaning the change $\Delta E_{\rm e}$ of electron kinetic energy is much smaller than the intial kinetic energy $E_{\rm e}$. The reason is that the energy $E_\gamma = h \nu$ of a radio photon is much smaller than the average kinetic energy of an electron in an HII region. This numerical comparison is an example of how astrophysical "intuition" leads to a simplification of the electron-ion scattering problem.
The mean electron energy in a plasma
of temperature $T$ is
$$E_{\rm
e} = {3 k T \over 2}$$
For an HII region with $T \sim
10^4$ K, this is
$$E_{\rm e} \approx {3 \times 1.38 \times
10^{-16} {\rm ~erg~K}^{-1} \times 10^4 {\rm ~K} \over 2} \approx 2
\times 10^{-12} {\rm ~erg~} \approx 1 {\rm ~eV} .$$
[This is another useful conversion
factor to remember: 1 eV is the typical energy associated with the
temperature $T \approx 10^4$ K.] The energy of a
photon is $E_\gamma = h \nu$. For example, a radio photon of frequency
$\nu = 10$ GHz has energy
$$E_\gamma \approx 6.63 \times 10^{-27} {\rm ~erg~s~} \times 10^{10}
{\rm ~Hz~} \approx 6.63 \times 10^{-17} {\rm ~erg~} \approx 4 \times
10^{-5} {\rm ~eV} .$$
The great inequality $E_\gamma \ll E_{\rm e}$ means that most radio
photons
are produced by weak interactions which cause the trajectory of the
electron to deflect
by only a small angle ($\ll 1$ radian). We may make the approximation
that
the electron path is nearly straight
as it interacts with an ion to
produce radio radiation.
During the interaction, the electron
will be accelerated
electrostatically both parallel to and perpendicular to its nearly
straight path:
$$F_\parallel = m_{\rm e} \dot{v}_\parallel = {Z e^2
\over l^2} \sin \psi = {Z e^2 \sin \psi \cos^2 \psi \over b^2}$$
$$F_\bot = m_{\rm e} \dot{v}_\perp = {Z e^2 \over l^2} \cos \psi =
{Z e^2 \cos^3 \psi \over b^2} ,$$
where $b$ is the
impact parameter
of the interaction, the minimum value of the distance $l$ between the
electron and the ion.
For a given
impact parameter $b$, the equations above can be solved to show that
the maximum of $\dot{v}_\parallel$ is actually about 0.38 $\times$ the
maximum of $\dot{v}_\perp$. Even so, the radio
radiation arising from $\dot{v}_\parallel$ is negligible. Plotting the
variation with time of $\dot{v}_\parallel$ and
$\dot{v}_\perp$ during the interaction shows pulses with quite
different shapes:

The pulse duration is $\tau \approx b /v$. The $\dot{v}_\parallel$ pulse is roughly a sine wave of frequency $\omega \sim \tau^{-1} \approx v / b$, which we will soon show is much higher than radio frequencies for all relevant impact parameters $b$. That is, the parallel acceleration produces infrared radiation but not radio radiation. The $\dot{v}_\perp$ pulse is a single peak whose frequency spectrum extends from zero up to $\sim v /b$ (recall that Fourier transform of a Gaussian is a Gaussian), so it is rich in radio frequencies.
Considering only the acceleration
perpendicular to the electron
velocity, we get the instantaneous power emitted from Larmor's formula:
$$P = {2 \over 3} {e^2 \dot{v}_\perp^2 \over c^3} = {2 e^2
\over 3 c^3} {Z^2 e^4 \over m_{\rm e}^2} \biggl( { \cos^3 \psi \over
b^2} \biggr)^2$$
The total energy $W$ emitted by the pulse is
$$W =
\int_{-\infty}^\infty P dt .$$
Since $(\Delta E_{\rm e}) / E_{\rm e} = E_\gamma / E_{\rm e} \ll
1$, we can make the approximation that the electron velocity is nearly
constant. From the
interaction diagram
we see that
$$ v = {d x \over d t} {\rm \quad~and~\quad} \tan \psi = {x \over
b}$$
so
$$v = {b d \tan \psi \over d t} = {b \sec^2 \psi d \psi
\over dt} = {b d \psi \over \cos^2 \psi dt}$$
and
$$d t = { b
\over v} { d \psi \over \cos^2 \psi}~.$$
The total pulse energy becomes
$$W =
\int_{-\infty}^\infty P d t = {2 \over 3} {Z^2 e^6 \over c^3 m_{\rm
e}^2 b^4} \int_{-\infty}^\infty \cos^6 \psi d t~.$$
By changing the variable of integration from $t$ to $\psi$ and then
invoking symmetry, we get
$$W = {2 \over 3} {Z^2 e^6 \over c^3 m_{\rm e}^2 b^4} \int_{-\pi /
2}^{\pi /2} {
b \over v} {\cos^6 \psi \over \cos^2 \psi} d \psi = {4 \over 3}
{Z^2
e^6 \over c^3 m_{\rm e}^2 b^3 v} \int_0^{\pi /2} \cos^4 \psi d
\psi$$
Evaluating
the integral yields
$$\int_0^{\pi/2} \cos^4 \psi d \psi = {3 \pi \over 16}$$
so the energy radiated by a single
electron-ion interaction
characterized by impact parameter $b$ and velocity $v$ is:
$$W = {\pi Z^2
e^6 \over 4 c^3 m_{\rm e}^2} \biggl( { 1 \over b^3 v} \biggr)$$
This energy is emitted in a single
pulse of duration $\tau \approx b
/v $, so the pulse
power spectrum
(the spectrum of the squared
Fourier components) is nearly flat over all frequencies $\nu <
\nu_{\rm max} \approx (2 \pi \tau)^{-1} \approx v /(2 \pi b)$ and falls
rapidly at
higher frequences. (Recall that the Fourier transform of a Gaussian is
a Gaussian.) In principle we could calculate the actual Fourier
transform of the pulse shape, but that would only introduce an
unnecessary complication into an already complicated calculation. The
ranges of velocities $v$ and impact parameters $b$ characterizing
electron-ion interactions in an HII region are so wide that
averaging over all collision parameters will wash out any fine detail
in
the spectrum associated with a particular $v$ and $b$.

The cutoff frequency $\nu_{\rm max}$ is much higher than any radio frequency; it corresponds to infrared radiation. As we will soon calculate, the typical electron speed in a $T \sim 10^4$ K HII region is $v \approx 7 \times 10^7$ cm s$^{-1}$ and the typical impact parameter is $b \approx 10^{-7}$ cm, so $\nu_{\rm max} \approx 10^{14}$ Hz, corresponding to the near-infrared wavelength $\lambda_{\rm min} \approx 3\mu$m.
We
make the approximation that the
power spectrum shown above is flat out to $\nu = \nu_{\rm max}$ and
zero at higher frequencies. Then the average energy per unit frequency emitted during a
single
interaction is approximately
$$W_\nu \approx {W \over \nu_{\rm max}} =\biggl( {\pi
Z^2 e^6 \over 4 c^3 m_{\rm e}^2 b^3 v} \biggr) \biggl( { 2 \pi b \over
v} \biggr)$$ $$W_\nu \approx {\pi^2 \over 2} {Z^2 e^6 \over c^3 m_{\rm
e}^2 } \biggl( { 1 \over b^2 v^2} \biggr) {\rm ,~~} \nu < \nu_{\rm
max} \approx {v \over 2 \pi b} \approx 10^{14} {\rm ~Hz}$$
Next we need to find the distributions of $v$ and $b$ to evaluate the radio emission from an HII region. The distribution of $v$ depends on the electron temperature $T$, and the distribution of $b$ depends on the electron number density $N_{\rm e}$ (cm$^{-3}$) and the ion number density $N_{\rm I}$ (cm$^{-3}$).
In LTE, the average kinetic energies
of electrons and ions are
equal. Since the electrons are much less massive, their speeds are much
higher, and we can make the approximation that the ions are nearly
stationary during an interaction.

Then the number of electrons passing
any ion per unit time with
impact parameter $b$ to $b + db$ and speed range $v$ to $v + dv$ is
$$N_{\rm e} (2 \pi b d b) v f(v) dv~.$$
Here $f(v)$ is the
normalized ($\int f(v) dv = 1$) speed distribution of the electrons.
The number $N(v,b)$ of
such encounters per unit volume per unit time is given by $$N(v,b)
dv db = (2 \pi b db) [v f(v) dv] N_{\rm e} N_{\rm i} .$$
The
spectral power at frequency $\nu$ emitted isotropically per unit volume
will be $4 \pi \epsilon_\nu$, where $\epsilon_\nu$ is the familiar
emission coefficient from radiative
transfer. Thus
$$4 \pi
\epsilon_\nu = \int_{b = 0}^\infty \int_{v = 0}^\infty W_\nu (v, b)
N(v, b) dv db$$
Substituting the results above gives
$$4 \pi
\epsilon_\nu = \int_{b = 0}^\infty \int_{v = 0}^\infty \biggl( { \pi^2
Z^2 e^6 \over 2 c^3 m_{\rm e}^2 b^2 v^2} \biggr) 2 \pi b db
N_{\rm e} N_{\rm i} v f(v) dv$$
$$4 \pi \epsilon_\nu = {\pi^3 Z^2
e^6 N_{\rm e} N_{\rm i} \over c^3 m_{\rm e}^2} \int_{v = 0}^\infty
{f(v) \over v} dv \int_{b = 0}^\infty {d b \over b}$$
You can see
right away that we have run into a problem: the integral
$$\int_{b =
0}^\infty {db \over b}$$
diverges logarithmically. There must be some
physical limits on the range of the impact parameter $b$ that prevent
this divergence. For the time being we will just call those limits
$b_{\rm
min}$ and $b_{\rm max}$; later we will identify their physical meanings
and evaluate them numerically. Meanwhile, $$4
\pi \epsilon_\nu = {\pi^3 Z^2 e^6 N_{\rm e} N_{\rm i} \over c^3 m_{\rm
e}^2} \int_{v = 0}^\infty {f(v) \over v} dv \int_{b_{\rm
min}}^{b_{\rm max}} {d b \over b}$$
The distribution $f(v)$ of electron
speeds in LTE is the nonrelativistic
Maxwellian distribution
$$\bbox[border:3px blue solid,7pt]{f(v) =
{4 v^2 \over \sqrt{\pi}} \biggl( { m \over 2 k T} \biggr)^{3/2} \exp
\biggl( - {m v^2 \over 2 k T} \biggr)}\rlap{\quad \rm {(4B1)}}$$
(see the derivation here or
in
any thermodynamics textbook such as
Kittel's Elementary
Statistical Physics).
Having $f(v)$ we can now evaluate the
integral over the electron
speeds:
$$ \int_{v = 0}^\infty { f(v) \over v} dv = {4 \over
\sqrt{\pi}} \biggl( { m_{\rm e} \over 2 k T} \biggr)^{3/2} \int_{v =
0}^\infty v \exp \biggl( - { m_{\rm e} v^2 \over 2 k T} \biggr)
dv
.$$
Let
$u \equiv m_{\rm e}v^2 / (2 k T)$ so $du = mv dv / (kT)$:
$$ \int_{v
= 0}^\infty { f(v) \over v} dv = {4 \over \sqrt{\pi}} \biggl(
{m_{\rm e} \over 2 k T} \biggr)^{3/2} \int_{u = 0}^\infty {k T \over
m_{\rm e}} e^{-u} du = {4 \over \sqrt{\pi} 2} \biggl( { m_{\rm e}
\over 2 k T} \biggr)^{1/2} \int_{u = 0}^\infty e^{-u} du$$
$$\int_{v=0}^\infty {f(v) \over v} dv = \biggl( {2 m_{\rm e}
\over \pi k T} \biggr)^{1/2}$$
In conclusion, we have the following
equation for
the free-free
emission coefficient:
$$\bbox[border:3px blue solid,7pt]{\epsilon_\nu = {\pi^2 Z^2 e^6 N_{\rm
e} N_{\rm i} \over 4 c^3
m_{\rm e}^2 } \biggl( {2 m_{\rm e} \over \pi k T} \biggr)^{1/2} \ln
\biggl( {b_{\rm max} \over b_{\rm min}} \biggr)}\rlap{\quad \rm
{(4B2)}}$$
The next problem is to estimate
the minimum and maximum
impact parameters $b_{\rm min}$ and $b_{\rm max}$. Since only the
logarithms of both parameters are needed, these estimates don't have to
be precise.
To estimate the minimum impact
parameter $b_{\rm min}$, we note that the net momentum impulse
$$\Delta P = \int_{-\infty}^{\infty} f dt = \int_{-\infty}^{\infty}e E
dt$$
comes from $E_\perp = E \cos \psi$ only because the contribution from
$E_\parallel$ is antisymmetric about $t = 0$. Thus
$$\Delta P = \int_{-\infty}^{\infty} e {Z e \cos \psi \over l^2} dt
= Z e^2 \int_{-\infty}^{\infty} {\cos^3 \psi \over b^2} dt$$
Changing the variable of integration from $t$ to $\psi$ using
$$ dt = {b \over v} d \tan \psi = {b \over v} \sec^2 \psi d \psi $$
gives
$$\Delta P = {Z e^2 \over b v} \int_{-\pi /2}^{\pi /2} \cos \psi d \psi
=
{2 Z e^2 \over b v}$$
The maximum possible momentum transfer during the interaction is twice
the initial momentum $m_{\rm e} v$ of the electron, so
$$\bbox[border:3px blue solid,7pt]{b_{\rm min} \approx {Z e^2 \over
m_{\rm e} v^2}}\rlap{\quad \rm {(4B3)}}$$
This result comes from a purely
classical treatment
of the interaction (See also Jackson's Classical Electrodynamics,
section 13.1 and problem 13.1, for a more detailed discussion). The
uncertainty principle does
imply a quantum-mechanical limit
$$b_{\rm min} = {\hbar \over m_{\rm e} v}~,$$
but this lower limit is generally smaller than the classical limit in
HII
regions and hence may be ignored. Following Jackson, section
13.3, we define $\eta$ is the ratio of the classical to quantum limits
$$ \eta = {Z e^2 \over 3 k T} / {\hbar \over m_{\rm e} v} =
{Z e^2 \over \hbar v} $$
For an HII region with $T \approx 10^4$, $ v \approx (3 k T /
m_{\rm e})^{1/2}$ and $\eta \approx 3$, so the classical limit applies.
Only for unusually cold plasmas, $T \ll 1000$ K, would the
quantum-mechanical limit be needed.
There are two ways to estimate the
relevant upper limit $b_{\rm max}$ to the impact parameter. Because
electrostatic forces always dominate gravity on small scales, electrons
in the vicinity of a nearly stationary ion are free to rearrange
themselves to neutralize, or shield, the ionic charge. The
characteristic scale length of this shielding is called the Debye
length. From Jackson's Classical Electrodynamics,
the
Debye
length is roughly
$$D \approx \biggl( { k T \over 4 \pi N_{\rm e} e^2 } \biggr)^{1/2}$$
The Debye length is quite large in the low-density plasma of a typical
HII region. For example, if $T \approx 10^4$ K and $N_{\rm e}
\approx 10^3$ cm$^{-3}$,
$$D \approx \biggl[ { 1.38 \times 10^{-16} {\rm ~erg~K}^{-1} \times
10^4 {\rm ~K} \over 4 \pi \times 10^3 {\rm ~cm}^{-3} \times (4.8 \times
10^{-10} {\rm ~statcoulomb})^2 } \biggr]^{1/2} \approx 22 {\rm ~cm}.$$
An independent upper limit to the
impact parameter is the largest value of $b$ that can generate a
significant amount of power at some relevant radio frequency $\nu$.
Recall that the pulse power per unit bandwidth is small above angular
frequencies
$$\omega \approx {v \over b}$$
so
$$ b_{\rm max} \approx {
v \over \omega} = {v \over 2 \pi \nu},$$
where $\nu$ is the radio frequency being considered.
Clearly, the relevant upper limit $b_{\rm max}$ in any particular situation is the smaller of these two upper limits. To see which is smaller, we calculate the limits for a typical HII region and a typical radio frequency.
Example: Estimate $b_{\rm min}$ and $b_{\rm max}$ for a pure HII region ($Z = 1$) with $T \approx 10^4$ K observed at $\nu = 10$ GHz $= 10^{10}$ Hz.
$$b_{\rm min} \approx {Z e^2 \over
m_{\rm e} v^2} \approx {Z e^2 \over 3 k T
}$$
$$b_{\rm min} \approx { (4.8 \times 10^{-10} {\rm ~statcoulomb})^2
\over 3 \times 1.38 \times 10^{-16} {\rm ~erg~K}^{-1} \times 10^4 {\rm
~K}}
\approx 5.6 \times 10^{-8} {\rm ~cm}$$
$$b_{\rm max} \approx {v \over 2 \pi
\nu} \approx \biggl( { 3 k T \over m_{\rm e} } \biggr)^{1/2} / (2 \pi
\nu)$$
so the largest impact parameter giving significant power at $\nu =
10^{10}$
Hz is
$$ b_{\rm max} \approx \biggl( { 3 \times 1.38 \times 10^{-16} {\rm
~erg~K
}^{-1} \times 10^4 {\rm ~K} \over 9.1 \times 10^{-28} {\rm ~g} }
\biggr)^{1/2} / ( 2 \pi \times 10^{10} {\rm s}^{-1} ) \approx 1.1
\times 10^{-3} {\rm ~cm}.$$
The maximum impact parameter capable of generating power at radio
frequencies is much smaller than the Debye length in an HII
region, so the Debye length is irrelevant. It takes so long for an
electron to move a $D \approx 22$ cm Debye length that it emits only at
unobservably low frequencies ($\nu < 1
$ MHz). The Debye length becomes relevant only in very dense plasmas
such as the solar chromosphere ($N_{\rm e} \approx 10^{12}$ cm$^{-3}$).
Our simple estimate of the ratio
$${b_{\rm max} \over b_{\rm min} } \approx \biggl( { 3 k T \over m_{\rm
e} } \biggr)^{1/2} (2 \pi \nu)^{-1} \biggl(
{ 3 k T \over Z e^2} \biggr) \approx \biggl( { 3 k T \over m_{\rm e} }
\biggr)^{3/2} { m
_{\rm e} \over 2 \pi Z e^2 \nu}$$
is very close to the result of Oster's (1961, Rev. Modern Physics, 33,
525) very detailed derivation and presented as Equation 9.29 in the
textbook. Next we note that the ratio $(b_{\rm max} / b_{\rm min})$ is
roughly $10^4$, which is much greater than the fractional velocity
range $\sigma_v / v \approx 1$ in the Maxwellian velocity distribution.
Also note that
$$
\ln \biggl({b_{\rm max} \over b_{\rm min}} \biggr) \sim 10$$
varies slowly with changes in either $b_{\rm max}$ or $b_{\rm min}$, so
small uncertainties in these limits have little effect on the
calculated emission coefficient of an HII region.
Since the HII region is in local
thermodynamic equilibrium (LTE) at some temperature $T$, we can use
Kirchoff's
law to calculate the absorption coefficient from the
emission coefficient and the blackbody brightness law: $$\kappa_\nu = {
\epsilon_\nu \over B_\nu(T)}~.$$
In the Rayleigh-Jeans limit
$$\kappa
_\nu = {\epsilon_\nu c^2 \over 2 k T \nu^2}$$
and
$$\bbox[border:3px blue solid,7pt]{\kappa_\nu = {1 \over \nu^2 T^{3/2}
} \biggl[ {Z^2 e^6 \over c}
N_{\rm e} N_{\rm i} {1 \over \sqrt { 2 \pi (m_{\rm e} k)^3 } } \biggr]
{\pi^2 \over 4} \ln \biggl( { b_{\rm max} \over b_{\rm min} }
\biggr)}\rlap{\quad \rm {(4B4)}}$$
Because the $b_{\rm max}$ varies slowly with frequency, the absorption coefficient is not exactly proportional to $\nu^{-2}$. A good numerical approximation is $\kappa _\nu \propto \nu^{-2.1}$.
The total opacity $\tau_\nu$ of an
HII region is the integral of $
-\kappa_\nu$ along the line of sight.

$$ \tau_\nu = \int_{\rm los} -\kappa_\nu ds \propto \int { N_{\rm e} N_{\rm i} \over \nu^{2.1} T^{3/2} } ds \approx \int { N_{\rm e}^2 \over \nu^{2.1} T^{3/2} } ds$$
At frequencies low enough that
$\tau_\nu \gg 1$, the HII region becomes opaque, its spectrum
approaches that of a black body with temperature $T \sim 10^4$ K, and
the flux density varies as $S \propto \nu^2$. At very
high frequencies, $\tau_\nu \ll 1$, the HII region is nearly
transparent, and
$$S_\nu \propto {2 k T \nu^2 \over c^2} \tau_\nu \propto \nu^{-0.1}$$
On a log-log plot, the overall spectrum of a uniform HII region looks
like this, with the spectral break corresponding to the frequency at
which $\tau_\nu \approx 1$:

The spectral slope on a log-log plot
is often called the
spectral index
and denoted by $\alpha$. Thus
$$\alpha \equiv \pm {d \log S \over d \log \nu}$$
Beware the $\pm$ sign!
Unfortunately both conventions are found in the
literature, and you have to look carefully at each paper to find out
which one is being used. With the $+$ sign convention, the
low-frequency spectral index of a uniform HII region would be $\alpha =
+2$. The $-$ convention was introduced in the early days of radio
astronomy because most sources discovered at low frequencies are
stronger at low frequencies than at high frequencies. Thus $\alpha =
+0.7$ might mean
$${d \log S \over d \log \nu} = -0.7$$
The spectrum of an inhomogeneous HII region will be similar well above
the break frequency, but the break will be more gradual and the
low-frequency slope will be somewhat less than +2. For example, ionized
winds from stars are quite inhomogeneous. Mass conservation in a
steady, constant-velocity, isothermal
spherical wind implies that the electron density is inversely
proportional to the square of the distance from the star: $N_{\rm e}
\propto r^{-2}$. The
low-frequency spectral spectral slope of free-free emission by such a
wind is closer to $+0.6$ than $+2$.
In the astronomical literature you
will encounter the term
emission
measure (EM) defined by the integral of $N_{\rm e}^2$
along the line-of-sight and usually expressed in astronomically
convenient units:
$$\bbox[border:3px blue solid,7pt]{{ EM \over {\rm pc~cm}^{-6} } \equiv
\int_{\rm los} \biggl( { N_e \over
{\rm cm}
^{-3} } \biggr)^2 d \biggl( { s \over {\rm pc}} \biggr) }\rlap{\quad
\rm {(4B5)}}$$
Since $\kappa_\nu$ is proportional to $N_{\rm e} N_{\rm i} \approx
N_{\rm e}^2$, the optical depth $
\tau$ is proportional to the emission measure. The emission measure is
commonly used to parameterize $\tau$ in astronomically convenient
units:
$$\tau_\nu \approx 3.014 \times 10^{-2} \biggl( { T_{\rm e} \over {\rm
K} } \biggr)^{-3/2} \biggl( { \nu \over {\rm GHz}} \biggr)^{-2} \biggl(
{ EM \over {\rm pc~cm}^{-6}} \biggr) \langle g_{\rm ff} \rangle~,$$
where the free-free Gaunt
factor
$\langle g
_{\rm ff} \rangle$ absorbs the slow frequency dependence associated
with the logarithmic term in $\kappa_\nu$:
$$\langle g_{\rm ff} \rangle \approx \ln \biggl[ 4.955 \times 10^{-2}
\biggl( {\nu \over {\rm GHz}} \biggr)^{-1} \biggr] + 1.5 \ln \biggl( {
T_{\rm e} \over {\rm K}} \biggr)$$
We end up with a very good approximation for free-free
opacity that is easy to evaluate
numerically:
$$\bbox[border:3px blue solid,7pt]{\tau_\nu \approx 3.28 \times 10^{-7}
\biggl( {T_{\rm e} \over 10^4
{\rm ~K} } \biggr)^{-1.35} \biggl( {\nu \over {\rm GHz} }
\biggr)^{-2.1} \biggl( { EM \over {\rm pc~cm}^{-6} }
\biggr)}\rlap{\quad \rm {(4B6)}}$$
From the optical depth $\tau$ and the electron temperature $T_{\rm e}$
we can
calculate the brightness temperature $T_{\rm b}$:
$$T_{\rm b} = T_{\rm e} (1 - e^{-\tau}
)~.$$
We don't know the structure of the HII region along the line-of-sight,
so it is common to approximate the geometry of an HII region by a
circular cylinder whose axis lies along the line-of-sight, and whose
axis length equals its diameter. We also suppose that the temperature
and density are constant throughout this volume. Then it is very easy
to estimate physical parameters of the HII region (e.g., electron
density, temperature, emission measure, production rate $N_{\rm Ly}$ of
ionizing photons) from the observed radio spectrum, once the distance
to the HII region is known (see problem set 5).
A useful approximation relating the
production rate of ionizing photons to the free-free
spectral
luminosity $L_\nu$ at high frequencies (where $\tau \ll 1$) of
an HII
region in ionization equilibrium is
$$\bbox[border:3px blue solid,7pt]{\biggl( { N_{\rm Ly} \over {\rm
s}^{-1} } \biggr) \approx 6.3 \times
10^{52} \biggl( { T_{\rm e} \over 10^4 {\rm ~K} } \biggr)^{-0.45}
\biggl( { \nu
\over {\rm GHz} } \biggr)^{0.1} \biggl( { L_\nu \over 10^{20} {\rm
~W~Hz}^{-1} } \biggr)}\rlap{\quad \rm {(4B7)}}$$
Example: The interstellar medium of our Galaxy contains a diffuse ionized component, some of which is "warm" ($T_{\rm e} \approx 10^4$ K) and some is "hot" ($T_{\rm e} \approx 10^6$ K). These two phases are roughly in pressure equilibrium so the hot medium is less dense by a factor of $\sim10^2$. The combination of high $T_{\rm e}$ and low $N_{\rm e}$ of the hot phase means that only the warm component contributes significantly to the free-free opacity of the ISM. There must be some frequency $\nu$ below which the disk becomes opaque and we cannot see out of the Galaxy, even in the direction perpendicular to the disk.
From the observed brightness spectrum
in the direction perpendicular to the disk, Cane (1979, MNRAS, 189,
465) found that $\tau \approx 1$ at $\nu \approx 3$ MHz. We can use
this result to estimate the typical electron density in the warm ISM.
$$ 1 \approx 3.28 \times 10^{-7} \times (1)^{-1.35} \times
{0.003}^{-2.1} \times \langle N_{\rm e}^2 \rangle \times 1000 {\rm
~pc}$$
$$\langle N_{\rm e}^2 \rangle^{1/2} \approx \biggl( { 0.003^{2.1} \over
3.28 \times 10^{-4} } \biggr)^{
1/2} \approx 0.1 {\rm ~cm}^{-3}$$
Free-free emission accounts for about
10% of the 1 GHz continuum luminosity in most spiral galaxies. It is
the strongest component in the frequency range from $\nu \approx 30$
GHz to $\nu \approx 200$ GHz, above which thermal emission from cool
dust grains dominates. Free-free absorption flattens the low-frequency
spectra of spiral galaxies, and the frequency at which $\tau \approx 1$
is higher in galaxies with high star-formation rates, especially if the
star formation is confined to a compact region near the nucleus.
